For sustainable growth, companies must be able to simultaneously pursue economic and social values based on entrepreneurial orientation. However, study on the complementary value creation process of entrepreneurial orientation (EO), technological innovation (TI), and ESG(Environmental, Social, and Governance) is very insufficient. Therefore, in this study, the effect of entrepreneurial orientation of domestic companies on the Sustainable Growth Rate (SGR) and the mediating effect of technological innovation and the moderating effect of ESG on their relationship were explored through GLS regression analysis and conditional indirect effect analysis. According to the analysis results, it was found that entrepreneurial orientation had a positive effect on the sustainable growth rate through technology innovation, and the mediating effect of technological innovation was stronger in companies with high ESG ratings. The results suggest that the creation of complementary effects between ESG strategies to create intangible assets and technological innovation that converts intangible assets into economic performance is becoming an important factor for the sustainable growth of companies. This study provides an empirical basis that companies should organically combine technological innovation and ESG for sustainable growth, and through this, useful implications for establishing corporate management strategies and policies are presented.